Recycled XPS typically undergoes multiple thermal histories, degrading molecular chains and increasing aged products (oligomers, styrene monomer). Detection methods: 1) Microscopic cell structure observation – recycled material shows uneven cell sizes and black impurities; 2) Melt flow index measurement – recycled material MFI increases (>10 g/10min); 3) UV spectroscopy to measure styrene monomer content (excess indicates recycled content); 4) TGA shows altered mass loss peak shape around 350°C. Engineering risks: recycled material shows accelerated compressive creep, with 5–10% thickness loss within 5 years; peel strength with metal facings drops by 50% due to low molecular weight exudates; and during fire, it releases more toxic black smoke.

